Research Progress | Chem. Mater. New Progress of Material Genome Approach Method for High-temperature Resistant Resin Design

Due to the advantages of light weight and high strength, high temperature resistant resin is widely used in the field of aerospace. At present, although the preparation of reinforcement materials such as carbon fiber has made great progress, the development of supporting resin is still relatively lagging behind, which has become the bottleneck restricting the improvement of composite properties. Since the commercialization of phenolic resin in 1909, high-temperature-resistant resin has developed for more than 100 years, from which many excellent resin systems have been born, and the service temperature has increased from the original 100 ℃ to the current mainstream 400 ℃. The current question is: can the service temperature of the resin be increased by a little, and can the speed of resin replacement be accelerated to meet the further needs of the aerospace field? In addition, from the perspective of processing, the curing temperature of the resin should be reduced as much as possible to improve the processing performance. However, the contradiction between improving the heat resistance and reducing the curing temperature is common in the design of thermosetting resin, just like you can't have your cake and eat it too, which brings great difficulties to the design of high-temperature-resistant resin.

Recently, Professor Jiaping Lin's group at East China University of Science and Technology has made a breakthrough in the design method of high-temperature-resistant-resin, established a material genome approach suitable for the design of high-performance polymers, greatly accelerated the research and development rate of resin, and expected to change the traditional material design method based on trial and error. The work was published in Chem.Mater. (DOI:/10.1021/acs.chemmater.0c00238)an important journal in the field of material chemistry, under the title of Rational Design of Heat-Resistant Polymers with LowCuring Energies by a Materials Genome Approach. The developed material genome approach methods include gene definition, collection and combination, performance prediction, structure screening, performance verification and so on.

 

Figure 1. Material genome approach method for resin design

1.Gene definition, collection and combination. In principle, any atom or chemical group can be combined as a gene, but the resulting polymer is often difficult to synthesize. In order to enhance the feasibility of the synthesis, chemical monomers for synthesis were defined as genes, and combinatorial screening was carried out.
2.Performance prediction. Performance prediction is the basis of rapid screening, but there is no proxy model to predict thermal stability and curing temperature. Through data mining, the physical quantities that can represent thermal stability and curing temperature are found, which lays a theoretical foundation for quickly screening resins with good thermal stability and low curing temperature.
3.Structure screening. Due to a large number of candidate genes and resins, how to quickly screen the optimal resin is an important problem to be solved. A two-step strategy of coarse screening first and then selection is proposed, that is, first calculate the low-cost agent quantity, reduce the number of candidate resins through the first step of screening, and then find the preferred resin through the calculation of high-cost agent quantity, which improves the screening efficiency.
4.Performance verification. Through the above steps, a new type of high temperature resistant resin is successfully designed and obtained. It’s 5% thermal decomposition temperature is greater than 650 ℃ and its curing temperature is less than 250 . It is expected to be used for a short time at 600 ℃ and meet the demand for high temperature resistant resin in the aerospace field.

The work was completed by Junli Zhu, a doctoral student at East China University of Science and Technology, and Ming Chu, a master student, under the guidance of Associate Professor Liquan Wang. The research work has been guided by Professor Jiaping Lin and Professor Lei Du, a well-known expert in the field of high temperature resistant resins. With the goal of standing in the sky, it not only develops theoretical design methods, but also meets the needs of practical applications, and promotes the high-quality development of polymer material genome approach.

Reference
Junli Zhu#, Ming Chu#, Zuowei Chen, Liquan Wang*, Jiaping Lin*, Lei Du. Rational Design of Heat-Resistant Polymers with Low Curing Energies by a MaterialsGenome Approach. Chem. Mater. 2020,DOI: /10.1021/acs.chemmater.0c00238
Website
https://pubs.acs.org/doi/10.1021/acs.chemmater.0c00238


网页发布时间: 2020-05-20